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Breath of the Wild has such a subdued and atmospheric soundtrack most of the time, it's easy to forget that there are some absolute belters in there:
The orchestral themes for the boarding of the three divine beasts that have them are all fantastic, shame you only get to hear them once per playthrough.
Also a big fan of the Parasail Minigame theme, such an uplifting and memorable song for such a teeny tiny smidgen of the game's overall content.
They did a really great job with the music for the DLC dungeon/boss, they feel really special for what would be the "final" content of the game for most players, but they don't usurp the original final dungeon/boss theme that still comes after from a chronological perspective.
I can think of the Naboris chase theme, and the Rudania stealth theme actually, but "epic" orchestral tracks are usually totally lost on me. I don't dislike them; I just really do not notice them. They just blend into one, so never leave much of an impact. Definitely can't remember the Medoh chase music at all, but I can remember bits of the Ruta one if I try hard enough.
The DLC is kind of like an interquel, whereas you'd normally expect it to be a sequel or side story. They definitely managed to get that across thematically